Wednesday, January 7, 2026

Various resources on Evapotranspiration, as we treat it

 Following our session on Evapotranspiration, I am listing some relevant resources beyond what we have already shared. Videos from previous GEOframe Schools are available here, and recordings from this year's school will be posted soon.

Core Reading

The most mature presentation of the theory, particularly for the latter part, is D'Amato and Rigon (2025a). A brief Claude-generated summary is available here. The paper addresses more complex cases than those presented at the School, but the first part—the big leaf model—is complete and clear.
For a more extensive treatment of this material, I recommend starting with the theses by Michele Bottazzi and Concetta D'Amato.
https://water.usgs.gov/edu/gallery/evaporation-fog.html

The Resistance Model for ET

An explanation of the resistance model for evapotranspiration can be found in The Marvelous Physics of Plants, beginning at slide 33. Unfortunately, the accompanying video is in Italian.

Differentiating Soil Behavior from Transpiration

Further lectures covering the differentiation of soil behavior from transpiration are available in the BACI course materials. The advantage of this resource is that the blog page contains step-by-step references to Bottazzi's thesis.

For Those Who Want to Go Deeper

The tool to use is GEOSPACE, which is fully documented in Concetta D'Amato's thesis and in D'Amato et al. (2025b). A Claude-generated summary of this paper is also available on the shared page.

References

Musical coda

Tuesday, January 6, 2026

Minkowski functionals: Critical Limitations and Future Directions for Minkowski Functionals in Soil Hydrology

Go to Part I

 Revisiting the Hadwiger Theorem

In Part 1, we introduced Minkowski functionals as a mathematically complete framework for geometric characterization, grounded in the Hadwiger theorem. Let's examine this completeness claim more carefully, because understanding what it means—and what it doesn't mean, is crucial for applying these tools appropriately in soil hydrology.
The Hadwiger theorem states that any continuous, motion-invariant, and additive functional defined on convex bodies in n-dimensional Euclidean space can be expressed as a linear combination of exactly (n+1) Minkowski functionals. In three dimensions: volume, surface area, integral mean curvature, and Euler characteristic—no more, no fewer.
The theorem's elegance lies in its completeness for static geometric description. The motion-invariance property ensures that measurements don't depend on how we orient or position our coordinate system, while additivity means that measuring two separate objects equals the sum of measuring them individually (accounting correctly for any overlap). These four functionals capture all the geometric information that can be extracted from a spatial pattern in a coordinate-independent, additive way.
For soil hydrologists, the Hadwiger theorem provides mathematical assurance: when we use these four functionals to characterize water distribution, we're working with a complete geometric description under these mathematical constraints. There are no "hidden" geometric properties we're missing that satisfy motion-invariance and additivity.
But, and this is crucia, soil hydrology involves much more than static, isotropic geometry.

Critical Limitations: When Geometry Is Not Enough
While the Hadwiger theorem guarantees that Minkowski functionals provide a complete geometric characterization, we must recognize fundamental limitations when applying these tools to soil hydrology. The mathematical elegance should not obscure the physical complexity of water movement in soils.

The Problem of Motion-Invariance

The "motion-invariance" in Hadwiger's theorem means that geometric measurements don't depend on coordinate system orientation—rotate your sample, and the Minkowski functionals remain unchanged. This is a property of how we measure geometry, not a statement about physical processes.
But water flow in soils is profoundly direction-dependent:
Minkowski functionals, being isotropic measures, cannot capture this directional information. Consider a simple thought experiment: imagine a water configuration in soil where gravity acts downward. Now imagine the identical geometric configuration but with gravity acting upward. The Minkowski functionals would be identical, same volume, surface area, curvature, connectivity. Yet the hydraulic behavior would be completely different. Pendant drops stable under downward gravity would drain immediately under upward gravity. Perched water tables would behave entirely differently.
This is not a flaw in the mathematics, motion-invariance is precisely what makes Minkowski functionals so powerful as geometric descriptors. But it highlights that geometry alone cannot determine hydraulic behavior in the presence of directional forcing like gravity.

Discontinuities and Dynamic Transitions

Water movement in porous media is characterized by discontinuous events:
These are not smooth, continuous processes, they involve abrupt topological changes where clusters suddenly merge or disconnect, interfaces jump across geometrically controlled barriers, and connectivity changes instantaneously. Energy is dissipated in these events, creating irreversibility that contributes to hysteresis.
While Minkowski functionals can detect these transitions (for instance, through sudden jumps in the Euler characteristic when clusters merge), they describe only the "before" and "after" geometric states. They don't capture the dynamics of the transition:
  • The velocity fields during rapid interface motion
  • Pressure gradients and their relaxation
  • Energy dissipation during Haines jumps
  • Timescales of geometric evolution
  • Inertial effects during rapid events
The "continuity" property in Hadwiger's theorem refers to mathematical smoothness of the measure itself (small geometric changes produce small functional changes), not to the physical continuity of water distribution or flow processes. Real soil hydrology involves fundamental discontinuities that static geometry cannot capture.

History Dependence and Hysteresis

Perhaps most critically, Minkowski functionals provide only a static snapshot of geometry at a particular moment. They cannot inherently encode how the system arrived at that configuration, the drainage versus imbibition history that creates hysteresis.
Consider two soil samples at the same water content θ = 0.4. Sample A reached this state through drainage from saturation, while Sample B reached it through imbibition from dry conditions. They might even have identical Minkowski functionals, same volume (M₀ = 0.4 by definition), possibly similar surface areas, curvatures, and connectivity if the pore structure allows different geometric configurations at the same saturation.
Yet their hydraulic behavior will differ dramatically:
The drainage sample likely has pendant drops and isolated clusters in large pores, trapped by capillary barriers at pore throats. The imbibition sample probably has water preferentially filling small pores and coating surfaces as films. These geometric differences might be detectable by Minkowski functionals, but the reason for the difference, the process history, is not encoded in the geometry itself.
Hysteresis is fundamentally about path-dependence: the relationship between state variables depends on the history of transitions. Geometry alone, no matter how completely characterized, cannot capture this temporal causality without additional information about the process history.

What's Missing from Static Geometry

To fully characterize soil hydraulic behavior, we need information beyond what static geometry provides:
1. Flow directionality: Which pathways are active for flow in specific directions under gravity or pressure gradients? Two pore networks might have identical connectivity topology but completely different vertical versus horizontal permeability.
2. Dynamic connectivity: Not just whether clusters are geometrically connected, but how efficiently they transport water. This involves:
  • Tortuosity and path length distributions
  • Bottleneck locations and their sizes
  • Dead-end pores that contribute to storage but not transport
  • Interface mobility and contact line pinning
3. Process history: The sequence of wetting/drying events that determines:
  • Current interfacial configurations
  • Contact angles (which depend on whether surfaces are advancing or receding)
  • Which pores are filled or empty at a given capillary pressure
  • The distribution of trapped air or water ganglia
4. Temporal evolution:
  • Rates of geometric change and interface motion
  • Relaxation times toward equilibrium configurations
  • Characteristic timescales for different processes (capillary equilibration, gravity drainage, diffusive redistribution)
  • Dynamic versus quasi-static flow regimes
5. Energetic states: Not just geometric configuration but:
  • The energy landscape and barriers between different configurations
  • Metastable states and their stability
  • Energy dissipation during transitions
  • The thermodynamic distance from equilibrium
6. Mechanical coupling:
  • Soil deformation affecting pore geometry
  • Swelling and shrinkage during wetting/drying
  • Crack formation and closure
  • Aggregate structural changes

Comprehensive Bibliography

Hadwiger Theorem and Integral Geometry Foundations

  • Hadwiger, H. (1957). Vorlesungen über Inhalt, Oberfläche und Isoperimetrie. Springer-Verlag, Berlin.
  • Hadwiger, H. (1959). Normale Körper im euklidischen Raum und ihre topologischen und metrischen Eigenschaften. Mathematische Zeitschrift, 71(1), 124-140.
  • Klain, D. A., & Rota, G. C. (1997). Introduction to Geometric Probability. Cambridge University Press.
  • Schneider, R., & Weil, W. (2008). Stochastic and Integral Geometry. Springer-Verlag, Berlin.
  • Alesker, S. (1999). Continuous rotation invariant valuations on convex sets. Annals of Mathematics, 149(3), 977-1005.

Foundational Works on Minkowski Functionals

  • Mecke, K. R. (1998). Integral geometry in statistical physics. International Journal of Modern Physics B, 12(09), 861-899.
  • Mecke, K. R. (2000). Additivity, convexity, and beyond: applications of Minkowski functionals in statistical physics. In Statistical Physics and Spatial Statistics (pp. 111-184). Springer, Berlin.
  • Schröder-Turk, G. E., et al. (2011). Minkowski tensor shape analysis of cellular, granular and porous structures. Advanced Materials, 23(22-23), 2535-2543.
  • Michielsen, K., & De Raedt, H. (2001). Integral-geometry morphological image analysis. Physics Reports, 347(6), 461-538.
  • Mantz, H., et al. (2008). Utilizing Minkowski functionals for image analysis: a marching square algorithm. Journal of Statistical Mechanics: Theory and Experiment, 2008(12), P12015.

Applications to Porous Media

  • Arns, C. H., et al. (2002). Computation of linear elastic properties from microtomographic images: Methodology and agreement between theory and experiment. Geophysics, 67(5), 1396-1405.
  • Mecke, K. R., & Arns, C. H. (2005). Fluids in porous media: a morphometric approach. Journal of Physics: Condensed Matter, 17(9), S503-S534.
  • Armstrong, R. T., et al. (2016). Beyond Darcy's law: The role of phase topology and ganglion dynamics for two-fluid flow. Physical Review E, 94(4), 043113.
  • Hilfer, R., & Manwart, C. (2001). Permeability and conductivity for reconstruction models of porous media. Physical Review E, 64(2), 021304.
  • Thovert, J. F., et al. (2001). Grain reconstruction of porous media: application to a Bentheim sandstone. Physical Review E, 63(6), 061307.
  • Arns, C. H., et al. (2005). Accurate estimation of transport properties from microtomographic images. Geophysical Research Letters, 28(17), 3361-3364.

Soil Science and Hydrology Applications

  • Vogel, H. J., & Roth, K. (2001). Quantitative morphology and network representation of soil pore structure. Advances in Water Resources, 24(3-4), 233-242.
  • Vogel, H. J., et al. (2010). Quantification of soil structure based on Minkowski functions. Computers & Geosciences, 36(10), 1236-1245.
  • Schlüter, S., et al. (2014). Image processing of multiphase images obtained via X-ray microtomography: a review. Water Resources Research, 50(4), 3615-3639.
  • Peth, S., et al. (2008). Three-dimensional quantification of intra-aggregate pore-space features using synchrotron-radiation-based microtomography. Soil Science Society of America Journal, 72(4), 897-907.
  • Cousin, I., et al. (1996). Three-dimensional analysis of a loamy-clay soil using pore and solid chord distributions. European Journal of Soil Science, 47(4), 439-452.
  • Perret, J., et al. (1999). Three-dimensional quantification of macropore networks in undisturbed soil cores. Soil Science Society of America Journal, 63(6), 1530-1543.

Topology, Connectivity, and Percolation

  • Hunt, A. G., & Sahimi, M. (2017). Flow, transport, and reaction in porous media: Percolation scaling, critical-path analysis, and effective medium approximation. Reviews of Geophysics, 55(4), 993-1078.
  • Vogel, H. J. (1997). Morphological determination of pore connectivity as a function of pore size using serial sections. European Journal of Soil Science, 48(3), 365-377.
  • Vogel, H. J. (2000). A numerical experiment on pore size, pore connectivity, water retention, permeability, and solute transport using network models. European Journal of Soil Science, 51(1), 99-105.
  • Mecke, K. R. (1994). Integral geometry in statistical physics. International Journal of Modern Physics B, 12(09), 861-899.
  • Torquato, S. (2002). Random Heterogeneous Materials: Microstructure and Macroscopic Properties. Springer Science & Business Media.
  • Rintoul, M. D., & Torquato, S. (1997). Precise determination of the critical threshold and exponents in a three-dimensional continuum percolation model. Journal of Physics A: Mathematical and General, 30(16), L585.

Hysteresis, Non-Equilibrium, and Dynamic Processes

  • Berg, S., et al. (2013). Real-time 3D imaging of Haines jumps in porous media flow. Proceedings of the National Academy of Sciences, 110(10), 3755-3759.
  • Armstrong, R. T., & Berg, S. (2013). Interfacial velocities and capillary pressure gradients during Haines jumps. Physical Review E, 88(4), 043010.
  • McClure, J. E., et al. (2018). Geometric state function for two-fluid flow in porous media. Physical Review Fluids, 3(8), 084306.
  • Schlüter, S., et al. (2016). Pore-scale displacement mechanisms as a source of hysteresis for two-phase flow in porous media. Water Resources Research, 52(3), 2194-2205.
  • Armstrong, R. T., et al. (2014). Linking pore-scale interfacial curvature to column-scale capillary pressure. Advances in Water Resources, 46, 55-62.
  • Schlüter, S., et al. (2017). Time scales of relaxation dynamics during transient conditions in two-phase flow. Water Resources Research, 53(6), 4709-4724.
  • Rücker, M., et al. (2015). From connected pathway flow to ganglion dynamics. Geophysical Research Letters, 42(10), 3888-3894.

Curvature, Interfacial Area, and Thermodynamics

  • Hilpert, M., & Miller, C. T. (2001). Pore-morphology-based simulation of drainage in totally wetting porous media. Advances in Water Resources, 24(3-4), 243-255.
  • McClure, J. E., et al. (2016). Influence of phase connectivity on the relationship among capillary pressure, fluid saturation, and interfacial area in two-fluid-phase porous medium systems. Physical Review E, 94(3), 033102.
  • Porter, M. L., et al. (2009). Measurement and prediction of the relationship between capillary pressure, saturation, and interfacial area in a NAPL-water-glass bead system. Water Resources Research, 45(8), W08402.
  • Joekar-Niasar, V., & Hassanizadeh, S. M. (2012). Analysis of fundamentals of two-phase flow in porous media using dynamic pore-network models: A review. Critical Reviews in Environmental Science and Technology, 42(18), 1895-1976.
  • Hassanizadeh, S. M., & Gray, W. G. (1993). Thermodynamic basis of capillary pressure in porous media. Water Resources Research, 29(10), 3389-3405.
  • Niessner, J., & Hassanizadeh, S. M. (2008). A model for two-phase flow in porous media including fluid-fluid interfacial area. Water Resources Research, 44(8), W08439.

Computational Methods and Image Analysis

  • Ohser, J., & Schladitz, K. (2009). 3D Images of Materials Structures: Processing and Analysis. Wiley-VCH.
  • Legland, D., et al. (2016). MorphoLibJ: integrated library and plugins for mathematical morphology with ImageJ. Bioinformatics, 32(22), 3532-3534.
  • Schladitz, K., et al. (2006). Design of acoustic trim based on geometric modeling and flow simulation for non-woven. Computational Materials Science, 38(1), 56-66.
  • Lindquist, W. B., & Venkatarangan, A. (1999). Investigating 3D geometry of porous media from high resolution images. Physics and Chemistry of the Earth, Part A: Solid Earth and Geodesy, 24(7), 593-599.
  • Lindquist, W. B., et al. (2000). Pore and throat size distributions measured from synchrotron X-ray tomographic images of Fontainebleau sandstones. Journal of Geophysical Research: Solid Earth, 105(B9), 21509-21527.

Stochastic Reconstruction and Multiscale Analysis

  • Karsanina, M. V., & Gerke, K. M. (2018). Hierarchical optimization: Fast and robust multiscale stochastic reconstructions with rescaled correlation functions. Physical Review Letters, 121(26), 265501.
  • Gerke, K. M., et al. (2019). Improving watershed-based pore-network extraction method using maximum inscribed ball pore-body positioning. Advances in Water Resources, 140, 103576.
  • Yeong, C. L. Y., & Torquato, S. (1998). Reconstructing random media. Physical Review E, 57(1), 495-506.
  • Hilfer, R. (1991). Geometric and dielectric characterization of porous media. Physical Review B, 44(1), 60-75.
  • Jiao, Y., et al. (2007). Modeling heterogeneous materials via two-point correlation functions: Basic principles. Physical Review E, 76(3), 031110.
  • Tahmasebi, P., & Sahimi, M. (2012). Reconstruction of three-dimensional porous media using a single thin section. Physical Review E, 85(6), 066709.

Upscaling and Effective Properties

  • Wildenschild, D., & Sheppard, A. P. (2013). X-ray imaging and analysis techniques for quantifying pore-scale structure and processes in subsurface porous medium systems. Advances in Water Resources, 51, 217-246.
  • Blunt, M. J., et al. (2013). Pore-scale imaging and modelling. Advances in Water Resources, 51, 197-216.
  • Costanza-Robinson, M. S., et al. (2008). X-ray microtomography determination of air-water interfacial area-water saturation relationships in sandy porous media. Environmental Science & Technology, 42(7), 2949-2956.
  • Arns, C. H., et al. (2001). Cross-property correlations and permeability estimation in sandstone. Physical Review E, 72(4), 046304.
  • Knackstedt, M. A., et al. (2001). Percolation properties of the three-dimensional pore space in rocks. Physical Review E, 64(5), 056302.

Recent Developments and Advanced Topics

  • Lin, Q., et al. (2018). Minimal surfaces in porous media: Pore-scale imaging of multiphase flow in an altered-wettability Bentheimer sandstone. Physical Review E, 99(6), 063105.
  • Rabbani, A., et al. (2021). Review of data science trends and issues in porous media research with a focus on image-based techniques. Water Resources Research, 57(3), e2020WR028597.
  • Bultreys, T., et al. (2016). Fast laboratory-based micro-computed tomography for pore-scale research: Illustrative experiments and perspectives on the future. Advances in Water Resources, 95, 341-351.
  • Schlüter, S., et al. (2020). Time scales of relaxation dynamics during transient conditions in two-phase flow. Water Resources Research, 56(4), e2019WR025815.
  • Singh, K., et al. (2017). Dynamics of snap-off and pore-filling events during two-phase fluid flow in permeable media. Scientific Reports, 7(1), 5192.
  • Andrew, M., et al. (2014). Pore-scale imaging of geological carbon dioxide storage under in situ conditions. Geophysical Research Letters, 41(15), 5347-5354.

Persistent Homology and Advanced Topology

  • Edelsbrunner, H., & Harer, J. (2008). Persistent homology—a survey. Contemporary Mathematics, 453, 257-282.
  • Robins, V., et al. (2011). Percolating length scales from topological persistence analysis of micro-CT images of porous materials. Water Resources Research, 52(1), 315-329.
  • Kramár, M., et al. (2013). Quantifying force networks in particulate systems. Physica D: Nonlinear Phenomena, 283, 37-55.

Multiphase Flow and Interface Dynamics

  • Raeini, A. Q., et al. (2014). Modelling two-phase flow in porous media at the pore scale using the volume-of-fluid method. Journal of Computational Physics, 231(17), 5653-5668.
  • Ferrari, A., & Lunati, I. (2013). Direct numerical simulations of interface dynamics to link capillary pressure and total surface energy. Advances in Water Resources, 57, 19-31.
  • Zacharoudiou, I., et al. (2017). The impact of drainage displacement patterns and Haines jumps on CO2 storage efficiency. Scientific Reports, 8(1), 15561.

Minkowsky functionals (a way to track water movement in soil)

Go to part II 

Introduction

How do we truly characterize the spatial distribution of water in soil? Beyond simple metrics like water content or saturation, the geometry and topology of water distribution carry crucial information about soil hydraulic behavior. This is where Minkowski functionals offer a powerful mathematical framework, one that has been largely under-explored in soil hydrology despite its rich potential.
Minkowski functionals are mathematical measures that completely characterize the morphology of spatial patterns in Euclidean space. Originally developed in integral geometry, they provide a set of scalar descriptors that capture essential geometric and topological properties of spatial structures. In the context of soil hydrology, they offer a sophisticated way to quantify how water phases are distributed, connected, and structured within the pore space.


What Are Minkowski Functionals?

For a three-dimensional body or pattern, there are four Minkowski functionals, each capturing different geometric properties:
  • M₀ (Volume): The total volume occupied by the phase of interest (e.g., water)
  • M₁ (Surface Area): The total surface area of the interface between phases (e.g., water-air interface, water-soil interface)
  • M₂ (Mean Breadth/Integral Mean Curvature): Related to the total mean curvature of the surface, capturing how "curved" the interface is
  • M₃ (Euler Characteristic): A topological invariant that counts the number of connected components minus the number of handles (tunnels) plus the number of cavities
These functionals are additive, motion-invariant, and continuous, properties that make them particularly useful for analyzing complex spatial patterns. Importantly, they form a complete set of geometric measures under certain mathematical conditions, though they remain informative even for the non-convex structures found in porous media.

The Hadwiger Theorem: Why These Four?

The answer lies in a deep mathematical result called the Hadwiger theorem, proven by Hugo Hadwiger in 1957. This fundamental theorem in integral geometry states that any continuous, motion-invariant, and additive functional (called a valuation) defined on convex bodies in n-dimensional Euclidean space can be expressed as a linear combination of exactly (n+1) Minkowski functionals.
In three dimensions, this means these four functionals—volume, surface area, integral mean curvature, and Euler characteristic—form a complete basis for geometric description. There are no "missing" geometric properties that satisfy these natural mathematical requirements. This completeness distinguishes Minkowski functionals from ad-hoc geometric measures and provides theoretical assurance that we're capturing all the geometric information available in a coordinate-independent, additive framework.

The Euler Characteristic: Topology Meets Hydrology

The Euler characteristic (χ = M₃) deserves special attention in soil hydrology. For a three-dimensional pattern:
χ = N₀ - N₁ + N₂
where N₀ is the number of connected water clusters, N₁ is the number of tunnels or loops through the water phase, and N₂ is the number of isolated cavities within the water.
This topological descriptor reveals critical information about hydraulic connectivity. A high positive χ suggests many isolated water clusters (poor connectivity), while negative values indicate a well-connected network with many redundant pathways. This directly relates to hydraulic conductivity and capillary connectivity, fundamental properties governing water flow.
Consider a simple example: at high saturation during imbibition, water forms a continuous network with many interconnected pathways (negative χ). As drainage proceeds, this network fragments into increasingly isolated clusters, and χ increases, eventually becoming positive. The point where χ crosses zero marks a fundamental topological transition—from a connected network to a collection of isolated features.

Applications to Soil Water Dynamics

1. Characterizing Drainage and Imbibition Paths

During drainage, water typically fragments from a well-connected network into increasingly isolated clusters. The Euler characteristic tracks this transition: starting negative (connected network) and becoming positive (isolated clusters) as saturation decreases. The rate of change dχ/dθ could identify critical thresholds where major topological transitions occur, perhaps corresponding to air entry values or percolation thresholds.
During imbibition, the reverse process occurs, but hysteresis means the path differs. At the same water content, drainage configurations might show more isolated clusters while imbibition shows more connected films and wedges. Minkowski functionals could quantify these path-dependent differences, providing geometric signatures of hysteretic behavior beyond traditional water retention curves.
Imagine tracking all four functionals simultaneously during a drainage-imbibition cycle. We'd see not just how much water is present (M₀), but how its surface area (M₁), curvature distribution (M₂), and connectivity (M₃) evolve differently along drainage versus imbibition paths. These geometric trajectories could reveal fundamental aspects of hysteretic mechanisms.

2. Linking Pore Structure to Hydraulic Properties

The mean breadth (M₂) relates to interfacial curvature, which directly connects to capillary pressure via the Young-Laplace equation:
Pc = γ(1/r₁ + 1/r₂)
where γ is surface tension and r₁, r₂ are the principal radii of curvature. Tracking M₂ as a function of water content provides information about the distribution of capillary pressures in the system—essentially a geometric interpretation of the water retention curve.
The surface area functional (M₁) quantifies the extent of water-air interfaces, which is crucial for understanding interfacial phenomena, evaporation dynamics, and the energetics of water distribution. During evaporation, for instance, M₁ determines the total interfacial area available for vapor transport, while changes in M₂ reflect how the geometry of menisci evolves as drying proceeds.
Recent research has shown that interfacial area is not uniquely determined by water content and capillary pressure alone, it exhibits hysteresis and depends on flow history. Minkowski functionals provide tools to quantify this additional complexity.

3. Non-Equilibrium States and Hysteresis

One of the most intriguing applications is tracking non-equilibrium water distributions. During rapid infiltration or redistribution, water occupies configurations that differ from equilibrium states at the same water content. Minkowski functionals could distinguish these transient states by their geometric signatures.
For instance, pendant drops trapped during rapid drainage versus uniform film coatings during slow imbibition might have similar water contents but dramatically different Euler characteristics (many isolated clusters versus one connected film) and surface areas. This geometric information could inform models that go beyond equilibrium assumptions.
Consider infiltration into initially dry soil: water advances as a wetting front, creating fingering patterns or preferential flow paths depending on initial conditions and infiltration rate. The evolving Minkowski functionals during this transient process could reveal when and how the system transitions from non-equilibrium invasion patterns to more uniform, equilibrium-like distributions.

4. Scale-Dependent Analysis

By computing Minkowski functionals at different scales (through morphological operations like erosion and dilation), we can examine how geometric properties change across scales. This multiscale analysis could reveal how local pore-scale water distribution relates to effective continuum-scale hydraulic properties—a crucial link for upscaling.
For example, at fine scales we might observe highly fragmented water distributions with positive χ, but coarse-graining could reveal that these fragments form a connected network at larger scales (negative χ). This scale-dependent connectivity has direct implications for how we define effective hydraulic conductivity and for understanding the scale-dependence of hydraulic properties.
The technique of morphological operations—systematically growing or shrinking phases—allows us to explore the "thickness distribution" of water features. Thin films coating particles might disappear at modest coarse-graining, while thicker wedges and pore-body water persist. Tracking how Minkowski functionals change with scale provides a geometric signature of this hierarchical structure.

Relating to Hydraulic Models

The real power emerges when we connect these geometric descriptors to physically based models. Several promising directions include:
Connectivity-based conductivity: Using χ to parameterize how hydraulic conductivity depends not just on water content but on the topological structure of water distribution. A well-connected network (negative χ) should conduct much better than isolated clusters (positive χ) at the same saturation.
Capillary pressure distributions: Relating M₂ to the distribution of capillary pressures in the system, potentially informing multi-scale or dual-porosity models where different geometric domains have different characteristic pressures.
Interfacial area in evaporation: Incorporating M₁ into evaporation models, where the rate of water loss depends on the available interfacial area for vapor diffusion.
Geometric state variables: Developing constitutive relations where hydraulic properties are functions not just of water content, but of the complete set of Minkowski functionals, creating geometry-informed models that capture hysteretic and non-equilibrium behavior.
This could lead to a new class of hydraulic models where geometric descriptors serve as state variables alongside traditional quantities like water content and pressure. The challenge is developing these relationships in ways that are both physically meaningful and practically implementable.

Looking Ahead

Minkowski functionals provide a rigorous, mathematically complete framework for geometric characterization of water distribution in soils. They offer quantitative descriptors that capture volume, surface area, curvature, and connectivity—fundamental aspects of spatial organization that determine hydraulic behavior.
For soil hydrologists, these tools open new possibilities for understanding hysteresis, characterizing non-equilibrium states, and linking pore-scale geometry to continuum-scale properties. As imaging technologies advance and computational methods mature, geometry-based approaches may become increasingly central to how we model and predict water movement in soils.
However, geometry is only part of the story. In Part 2 of this series, we'll examine critical limitations of purely geometric approaches and explore how static spatial descriptors must be augmented with dynamic, directional, and historical information to fully capture the complexity of soil hydraulic processes.

Selected References 

Foundations and Theory

Soil and Porous Media Applications

  • Vogel, H. J., & Roth, K. (2001). Quantitative morphology and network representation of soil pore structure. Advances in Water Resources, 24(3-4), 233-242.
  • Vogel, H. J., et al. (2010). Quantification of soil structure based on Minkowski functions. Computers & Geosciences, 36(10), 1236-1245.
  • Schlüter, S., et al. (2014). Image processing of multiphase images obtained via X-ray microtomography: a review. Water Resources Research, 50(4), 3615-3639.

Connectivity and Topology

  • Mecke, K. R., & Arns, C. H. (2005). Fluids in porous media: a morphometric approach. Journal of Physics: Condensed Matter, 17(9), S503-S534.
  • Armstrong, R. T., et al. (2016). Beyond Darcy's law: The role of phase topology and ganglion dynamics for two-fluid flow. Physical Review E, 94(4), 043113.

Monday, January 5, 2026

Geometry and Thermodynamics of soils

Soil physics textbooks, often illustrated with a simple diagram of a pore shaped like an old ink bottle: a wide body connected to a narrow neck. While pedagogically useful, this explanation deserves closer scrutiny, particularly when we consider what actually drives hysteresis at the pore scale.

The ink-bottle model attempts to explain why soil water retention curves differ during wetting and drying, the phenomenon we call hysteresis. The argument is straightforward:

During drainage (drying), water trapped in the wide pore body cannot escape until the matric potential is low enough to drain through the narrow neck. The neck acts as a bottleneck, controlling when water leaves. This means water remains in the pore at higher suctions than the pore body size alone would suggest. This concept pairs with the idea of feasible optimality : the system reaches equilibrium not at the minimal energy configuration, but in an intermediate state compatible with the topology of the pore network configuration. The geometry constrains what thermodynamic states are accessible.

During wetting
, water enters through the narrow neck and fills the larger body once it passes through. The pore fills at a lower matric potential than it empties, creating the hysteretic loop. While this process may require time to complete, its final result approaches the minimal energy configuration allowed by the geometry.

The traditional criticism of the ink-bottle model is that it only works with very specific pore connectivity, that if you imagine soil as a simple bundle of separate capillary tubes, each pore fills and empties independently with no geometric trapping.

However, this criticism itself is based on an oversimplified geometry . Real soil pore networks are three-dimensional, interconnected structures with braided pathways where the pore radius varies continuously along each flow path. This is fundamentally different from either isolated capillaries or idealized ink-bottles.

In actual soils, as documented in the work of Or and Tuller (1999, 2004), pore spaces form complex 3D networks where:-Flow paths are not isolated tubes but interconnected channels with varying cross-sections
Pore throats and bodies alternate along any given pathway, creating natural "ink-bottle" geometries
Multiple throats converge to form larger pore spaces, then diverge again
Pore radii vary continuously rather than jumping between discrete sizes

When viewed in three dimensions, the ink-bottle configuration—wide bodies accessible through narrow throats—is not a special case but rather a generic feature of porous media structure .

This 3D perspective reveals that ink-bottle effects can indeed create non-equilibrium conditions, particularly where multiple narrow throats converge to wider pore bodies. During drainage, water trapped in these convergent zones cannot escape until the matric potential is sufficient to empty through the smallest controlling throat. During wetting, the sequence reverses but follows different pathways through the network.

Hysteresis emerges from the interplay of two distinct physical mechanisms operating together:

1. Geometric Ink-Bottle Effects (Pore Network Topology)Water distribution controlled by pore throat sizes in the connected network
Different filling/emptying sequences through the 3D braided structure
Path-dependent behavior arising from network connectivity

2. REV-Scale Non-Equilibrium (Pore-Scale Energy States)

The second mechanism operates at a different scale and through different physics:

During rapid wetting , water fills pores according to their spatial accessibility and network connectivity, not according to their equilibrium energy states. Water reaches pores based on which pathways are available through the network, creating an initial distribution that may be far from thermodynamic equilibrium. Redistribution toward equilibrium then requires a relaxation time that can be much longer than the timescale of flow. Water may be transported rapidly away from its initial position along large, well-connected pores before it has time to redistribute into smaller pores that would represent lower energy states.

Additional factors contributing to REV-scale non-equilibrium:
  • Non-uniform water distribution within individual pores : Even a single pore contains water in different states
  • Multiple energetic states : Water exists as capillary water, adsorbed films, and tightly-bound water with very different chemical potentials
  • Chemical potential gradients : These drive slow relaxation processes that may span hours to days

These geometric and REV-scale mechanisms operate together, not in isolation. The geometric structure determines which pores can access water at a given potential, while the REV-scale thermodynamic state determines how that water distributes within and among accessible pores. Even in a single, simple cylindrical pore, water doesn't distribute uniformly during drainage and wetting:

During drainage, water doesn't simply empty from pores in a binary fashion:
  • Water retreats from pore centers first as bulk capillary water drains
  • Thin films remain along pore walls, held by adsorptive forces
  • Water persists in corners and surface roughness features
  • These films exist with chemical potentials far below that of bulk water
Macroscopically the pore may appear "empty," but significant water remains—water that's thermodynamically distinct from the bulk phase.
During subsequent wetting, water advances into these partially dry pores from a completely different initial configuration:
  • Contact angles differ from those during drainage
  • The progression of wetting fronts follows different pathways
  • Film thickening kinetics create different water distributions
The final state depends on the entire wetting history, not just the current matric potential. Recognizing hysteresis as fundamentally a non-equilibrium phenomenon has profound implications: we need infiltration theories that don't assume local equilibrium at the REV scale .

The classical Richards equation approach assumes that at each point in the soil profile, water content and matric potential are in local thermodynamic equilibrium—related uniquely by the water retention curve. But if water distribution is inherently out of equilibrium during infiltration (both geometrically through network effects and at the REV scale through multi-timescale relaxation), this assumption breaks down precisely when we're trying to model infiltration.

A proper non-equilibrium infiltration theory must account for:

1. Kinetics of pore-scale redistribution : Water distribution lags behind the macroscopic pressure field, with different regions (capillary, adsorptive, tightly-bound) evolving on different timescales

2. Flux-dependent retention : The effective θ(ψ) relationship depends on the infiltration rate q. Higher fluxes lead to greater departures from equilibrium, with preferential filling of larger, more accessible pores

3. Adsorptive forces : The role of surface interactions in establishing water films that don't instantly equilibrate with bulk water pressure. For clay-rich soils, this can dominate the retention behavior

4. Path-dependence : The recognition that the current state depends on the entire infiltration history, not just current boundary conditions

Such a theory would treat infiltration not as instantaneous local equilibration, but as a process where pore-scale water distribution evolves dynamically, influenced by both current conditions and past states. The water retention curve becomes a trajectory in phase space rather than a unique constitutive relationship.
Understanding hysteresis as arising from both geometric network effects and REV-scale non-equilibrium fundamentally changes how we approach vadose zone hydrology:
Geometric network models capture pore connectivity and ink-bottle trapping through the 3D structure. These are essential for understanding how water accesses different regions of the pore space.
Equilibrium thermodynamic models assume retention curves uniquely describe the water state at each potential—missing both the network topology effects and the REV-scale non-equilibrium dynamics.

Non-equilibrium theories must integrate both aspects: the geometric constraints from 3D pore networks AND the REV-scale non-equilibrium within and among pores. The effective retention behavior emerges from:
  • Network topology : Ink-bottle trapping in braided 3D pore structures with varying throat/body sequences
  • Stochastic infiltration : Initial filling that doesn't respect equilibrium energy ordering
  • Multi-timescale relaxation : Fast capillary redistribution through the network, slow adsorptive equilibration within pores
  • Adsorptive forces : Creating energetically distinct water populations that relax on different timescales
  • Chemical potential gradients : Driving water redistribution both between pores (through throats) and within pores (films and bulk water)
  • Preferential flow : Both network connectivity (which pores are accessible) and stochastic filling (which accessible pores actually fill first)
  • Rate-dependent hysteresis : Network effects persist at all rates, while REV-scale non-equilibrium increases with faster processes
  • Mobile-immobile water : Geometrically trapped water in isolated pore bodies PLUS adsorbed water that equilibrates too slowly
  •  Lab-field discrepancy : Laboratory measurements at equilibrium miss both network-scale connectivity effects and field-scale REV non-equilibrium dynamics
The ink-bottle effect is real and important—not as a pedagogical simplification but as a fundamental manifestation of 3D pore network geometry. When we view soil pore spaces in their true three-dimensional complexity, configurations with varying throat and body sizes along interconnected pathways are ubiquitous.

However, geometry alone cannot explain the full richness of hysteretic behavior. The complete picture requires recognizing that geometric structure and REV-scale non-equilibrium work together : network topology determines which pores can participate in water retention, while REV-scale thermodynamic processes determine how water distributes within the accessible pore space and how quickly it approaches equilibrium.

Developing rigorous infiltration theory requires capturing both the spatial constraints of pore network connectivity and the temporal evolution of REV-scale thermodynamic states. This is not about choosing between geometric or thermodynamic explanations, but understanding how pore network topology and interfacial thermodynamics interact to create the path-dependent, rate-sensitive, history-aware behavior we call hysteresis.

Related to this post: Go to Minkowski functional posts


References for further reading:
  • Or, D., & Tuller, M. (1999). Liquid retention and interfacial area in variably saturated porous media: Upscaling from single-pore to sample-scale model. *Water Resources Research*, 35(12), 3591-3606.
  • Tuller, M., Or, D., & Dudley, L. M. (1999). Adsorption and capillary condensation in porous media: Liquid retention and interfacial configurations in angular pores. *Water Resources Research*, 35(7), 1949-1964.
  • Tuller, M., Or, D., & Hillel, D. (2004). Retention of water in soil and the soil water characteristic curve. *Encyclopedia of Soils in the Environment*, 4, 278-289.
  • Mualem, Y. (1984). A modified dependent-domain theory of hysteresis. *Soil Science*, 137(5), 283-291.
  • Lu, N., & Likos, W. J. (2004). *Unsaturated Soil Mechanics*. Wiley.
  • Hassanizadeh, S. M., & Gray, W. G. (1993). Thermodynamic basis of capillary pressure in porous media. *Water Resources Research*, 29(10), 3389-3405.
  • Celia, M. A., Reeves, P. C., & Ferrand, L. A. (1995). Recent advances in pore scale models for multiphase flow in porous media. *Reviews of Geophysics*, 33(S2), 1049-1057.


Wednesday, December 31, 2025

The Tricky Energy Budget of Freezing Soil: A Thermodynamic Framework for Understanding Phase Changes

Freezing soil presents unique challenges in understanding the coupled mass and energy dynamics within the Earth’s critical zone. This paper presents a comprehensive thermodynamic framework for analyzing phase transitions in soil-water-ice systems. We present a unified treatment based on non-equilibrium
thermodynamics, where temperature, pressure, and chemical potential act as primary driving forces. The framework accounts for freezing point depression through mechanisms including the Gibbs-Thomson effect, solute presence, ice nucleation, and surface interactions. We demonstrate how upscaling from pore-
scale thermodynamics to the Darcy scale introduces theoretical challenges in determining phase transformation rates and flux laws. The sequential freezing process, governed by water energetic states in different pore sizes, creates complex interplay between capillary forces and phase changes essential for modeling
https://mosaicworks.com/gallery/fineart/permafrost/

This paper is an evolution of the talk given last summer at PanAm Unsat 2025 conference that you can find here. Official, preprint will be soon available. Temporary preprint available here


Tuesday, December 23, 2025

After the feedback of the LinkedIn post

 Following my LinkedIn post, I've gained around fifty new followers and received several inquiries about the PhD and postdoc positions. While many CVs show promise, they often lack the specific background we're seeking. To be clear: we value genuine interest and appreciation of our research over purely academic credentials, but this commitment must be demonstrated, not just stated.

Before reaching out, I strongly encourage prospective candidates to enroll (free of charge) in our Winter School [info here and here]. The Winter School has already begun, but a motivated PhD candidate should be able to catch up on the material independently and address any gaps. If difficulties arise, you're welcome to ask questions, but the ability to work through challenges autonomously is precisely what we're looking for.

No pain, no gain!


P.S. - Although the Winter School could not available at the time of your application, please take time to explore our materials and understand our research approach. We appreciate candidates who show commitment through their preparation.

During interviews, we typically explore:

  • Your relevant skills for this specific project
  • Your programming capabilities and experience
  • Your motivation for not applying the Winter School (if you did not apply to any)
  • Your understanding of GEOframe and our research
  • Your availability and current commitments
  • Technical aspects specific to the project
  • The skills and expertise you've highlighted in your application (specificity is valued over generic statements)